Excess Molar Volume of Binary Mixtures of Tetrachloroethylene + Acetylacetone, + Acrylonitrile, + Anisole and + Tetrahydrofuran at 303.15 K
Keywords:
Tetrachloroethylene, dilatometer, excess volume, specific interaction.Abstract
Excess molar volumes have been measured by means of a dilatometer for tetrachloroethylene (TCE) +acetyl acetone, + acrylonitrile, +anisole and+ tetrahydrofuran at 303.15 K. VEm values are positive over the entire range of composition for TCE- anisole and TCE - acetyl acetone and negative for TCE- Tetrahydrofuran. For TCE - acrylontrile, VEm has been found to be negative up to x = 0.8379 and positive onward. Values of VmE for the various systems have been fitted by the method of least squares with smoothing equation, and have been discussed from the viewpoint of the existence of specific interactions between the components.
References
Tripathi AD. Excess enthalpies of Dibromomethane with acetone, 1, 4-dioxane, pyridine, diethyl ether, ethyl methyl ketone and tetrahydrofuran at 303.15 K. J Chem Eng Data 2010; 55: 1113-16. http://dx.doi.org/10.1021/je900547w
Tripathi AD. Excess molar enthalpies of Dibromomethane with benzene, methanol, dimethylsulfoxide and pyrrolidin- 2- one at 303.15 K. J Chem Eng Data 2010; 55: 1421-23. http://dx.doi.org/10.1021/je9005882
Tripathi AD. Dielectric Properties of Mixtures of Acetylene Tetrachloride with Toluene and Acetone. J Solution Chem 1994; 23(7): 769-76. http://dx.doi.org/10.1007/BF00972671
Chadha R, Tripathi AD. The excess molar enthalpies of mixing of 1, 1, 2, 2-tetrachloroethane with methylfuran, Tetrahydrofuran, 1,4-dioxane, and cyclopentanone at 308.15 and 318.15K. J Chem Eng Data 1995; 40: 645-46. http://dx.doi.org/10.1021/je00019a024
Pathak G, Tripathi AD, Phalgune UD, Pradhan SD. Enthalpies of mixing of tetrachloroethane with furan, methyl furan, tetrahydrofuran, cyclopentanone and 1,4,dioxane. Thermochim Acta 1995; 258: 109-15. http://dx.doi.org/10.1016/0040-6031(94)02236-H
Tripathi AD. The excess molar enthalpies of mixing of 1, 1, 2,2-tetrachloroethane with acetone, n-dibutyl ether, acetonitrile and dimethylsulphoxide. J Chem Eng Data 1995; 40: 1262-63. http://dx.doi.org/10.1021/je00022a025
Rastogi RP, Nath J, Singh B. Excess volumes for tetrachloroethylene + benzene, + toluene, + p-xylene, + carbon tetrachloride, and + cyclohexane at 303.15 K. J Chem Thermodyn 1977; 9(9): 831-34. http://dx.doi.org/10.1016/0021-9614(77)90168-9
Nath J, Tripathi AD. Binary systems of 1,1,2,2- tetrachloroethane with benzene, toluene p-xylene acetone and cyclohexane.1. Excess Volumes, Ultrasonic Velocities, and Adiabatic Compressibilities at 298.15 and 308.15 K. J Chem Eng Data 1983; 28: 263-66. http://dx.doi.org/10.1021/je00032a038
Nath J, Dixit AP. Excess volumes for liquid mixtures of Acetone with Benzene, Toluene, p-xylene, Mesitylene, and Cyclohexane. J Chem Eng Data 1983; 28(2): 190-91. http://dx.doi.org/10.1021/je00032a018
Mehta SK, Chauhan RK, Tripathi AD. Excess molar enthalpies of mixtures of pyrrolidin-2-one with methanol, or ethanol, or propan-1-ol, or butn-1-ol, or pentan-1-ol at the temperature 303.15 K. J Chem Thermodyn 1997; 29: 353-58. http://dx.doi.org/10.1006/jcht.1996.0163
Riddick W, Bunger WB. Organic solvents John Wiley, New York 1970.
Weast RC. CRC Handbook of Chemistry and Physics, 68th ed. (CRC Press, Florida, 1987-88).
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