Volumetric Study of the Binary Mixtures Containing a Branched Hexane and an Isomeric Chlorobutane
DOI:
https://doi.org/10.6000/1929-5030.2015.04.04.3Keywords:
Branched hexane, Isomeric chlorobutane, Prigogine-Flory-Patterson theory, Volumetric behaviourAbstract
This paper reports densities at atmospheric pressure and at three temperatures T = (283.15, 298.15, and 313.15) K of eight binary mixtures involving a branched hexane (3-methylpentane or 2,2-dimethylbutane) and each one of the isomeric chlorobutanes (1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane or 2-chloro-2-methylpropane). Excess volumes were calculated from experimental densities and correlated with the Redlich-Kister equation. Moreover, the excess volumes were analysed using the Prigogine-Flory-Patterson theory.
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Published
2015-12-18
How to Cite
Guerrero, H., Royo, F. M., & Lafuente, C. (2015). Volumetric Study of the Binary Mixtures Containing a Branched Hexane and an Isomeric Chlorobutane. Journal of Applied Solution Chemistry and Modeling, 4(4), 178–184. https://doi.org/10.6000/1929-5030.2015.04.04.3
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