The Existence of Two Types of Colloidal Solutions of Molecules Fullerene C60
DOI:
https://doi.org/10.6000/1929-5030.2017.06.02.2Keywords:
Fullerene C60 molecule, molecule diagram, colloidal solution, solubility isobar, solutions classificationAbstract
The last thirty years scientists carried out an active search of universal parameter of solvent C60 for predicting the solubility of fullerenes. However, this parameter was not found up to these days. In this paper it has been found an explanation of the impossibility of detection of such parameter.
In present paper the features of the solubility of fullerene C60 molecules in nonpolar solvents have been studied. The molecule state diagram of the fullerene С60 molecules in solution at temperatures 265+308 K and pressure range 1+100 MPa indicating the existence field of β and γ-modifications, has been constructed.
Moreover, it has been shown that in the solutions of fullerenes C60 in the γ-state the solubility decreases with a rise in temperature since the chemical activity of fullerene molecule increases. For this reason during extraction procedure the temperature rise causes the value of extraction rate to increase, but solubility – to decrease, i.e. to diminish the concentration of fullerenes molecules in the solvent volume.
References
[1] Kornilov MYu, Ljubchuk TV, Isaev SD, Panasyuk H, Chernogorenko VB, Schur DV. Perhydrofullerenes as accumulators of hydrogen. Molecular Materials 2000; 13: 285-90.
[2] Yu M Shulga, Tarasov BP, Koshyk D, Drahan V, Zaginaichenko S Yu. Hydride method of C60 fullerite production with “enlarged” fcc lattice. In: Proceed. Int. Symp. “Metal-Hydrogen Systems”, Australia, Queensland, Noosa. p. 196. 2000.
[3] Alekseyev NI, Dyuzhev GA. Fullerene formation in an arc discharge. Carbon 2003; 41: 1343-8. https://doi.org/10.1016/S0008-6223(03)00058-7
[4] Schur DV, Zaginaichenko S Yu, Veziroglu TN. Peculiarities of hydrogenation of pentatomic carbon molecules in the frame of fullerene molecule C60. Int J Hydrogen Energy 2008; 33: 3330-45. https://doi.org/10.1016/j.ijhydene.2008.03.064
[5] Schur DV, Zaginaichenko SYu, Lysenko EA, et al. The forming peculiarities of C60 molecule. In: Carbon Nanomaterials in Clean Energy Hydrogen Systems. Dordrecht, Netherlands: Springer. pp. 53-66, 2008.
[6] Schur DV, Matysina ZA, Zaginaichenko S Yu. Carbon nanomaterials and phase transformations in them. Monograph. Dnepropetrovsk, Ukraine: Science and education. 678 p, 2007. (in Russ.)
[7] Schur DV, Zaginaichenko S Yu, Veziroglu TN, Javadov NF. The peculiarities of hydrogenation of fullerene molecules C60 and their transformation (chapter 17). In: Proc. of NATO ARW on the Black Sea: Strategy for Addressing its Energy Resource Development and Hydrogen Energy Problems. Dordrecht, Netherlands: Springer. pp. 191-204, 2013. https://doi.org/10.1007/978-94-007-6152-0_17
[8] Anikina NS, Schur DV, Zaginaichenko S Yu, et al. Regularity of fullerene C60 dissolution in polymethyl-substituted benzenes. Nanosystems, Nanomaterials, Nanotechnologies 2013; 11: 173-92 (in Russ.).
[9] Schur DV, Zaginaichenko S Yu, Veziro?lu TN. The hydrogenation process as a method of investigation of fullerene C60 molecule. Int J Hydrogen Energy 2015; 40: 2742-62. https://doi.org/10.1016/j.ijhydene.2014.12.092
[10] Schur DV. The physico-chemical regularities of synthesis, extraction, crystallization processes and application of fullerene C60. Manuscript. Thesis of Dr. chem. sci. diss. Kiev, Ukraine. 336 p., 2014 (in Russ.)
[11] Schur DV, Zaginaichenko S Yu, Shulga Yu M, Anikina NS, Polyschuk M.A. Study of features of the salting-out process of fullerite from saturated solution of C60 in toluene. I. Laminar mixing of reagents. Nanosystems, Nanomaterials, Nanotechnologies 2013; 11: 815-32 (in Russ.).
[12] Schur DV, Zaginaichenko S Yu, Kotko AV, Anikina NS, Kamenetskaia E.A. Study of features of the salting-out process of fullerene from saturated solution of C60 in toluene. II. Turbulent mixing of reagents. Nanosystems, Nanomaterials, Nanotechnologies 2013; 11: 832-61 (in Russ.).
[13] Anikina NS, Krivuschenko O Ya, Mil’to OV, Zolotarenko EP, Schur DV, Zaginaichenko S Yu. The interaction of soluble carbon nanostructures with aromatic solvents. Nanosystems, Nanomaterials, Nanotechnologies 2013; 11: 193-216 (in Russ.).
[14] ?nikina NS, Krivuschenko O Ya, Schur DV, Zaginaichenko S Yu, Kamenetskaia EA. Special features and regularities of interaction between fullerene molecules and aromatic solvents (chapter 4). In: Carbon Nanomaterials in Clean Energy Hydrogen Systems. Dordrecht, Netherlands: Springer. pp. 53-74, 2011. https://doi.org/10.1007/978-1-4020-5514-0_2
[15] Anikina NS, Schu, DV, Zaginaichenko S Yu, Krivuschenko O Ya, Kale A. Investigation of mechanism of fullerene dissolution in aromatical hydrocarbons. In: Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. Dordrecht, Netherlands: Springer. pp. 19-36, 2007.
[16] Ruoff RS, Malhotra R, Huestis DL, Tse DS, Lorents DC. Anomalous solubility behavior of C60. Nature 1993; 362: 140- 1. https://doi.org/10.1038/362140a0
[17] Sawamura S, Fujita N. High-pressure solubility of fullerene C60 in toluene. Carbon 2007; 45: 965-70. https://doi.org/10.1016/j.carbon.2006.12.030
[18] Matysina ZA, Zaginaichenko S Yu, Schur DV, et al. C60 fullerite solubility in organic matrix. Nanosystems, Nanomaterials, Nanotechnologies 2009; 7: 671-81 (in Russ.).
[19] Matysina ZA, Zaginaichenko S Yu, Schur DV. The solidphase transformations in fullerite stimulated by rearrangement of structure of fullerene molecules. Metal Physics and Advanced Technologies 2009; 31: 987-1000 (in Russ.).
[20] Khotynenko NG, Schur DV, Zaginaichenko S Yu, et al. On electrochemical deposition of fullerenes and their compounds from solutions. In: Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. Dordrecht, Netherlands: Springer. pp. 287-299, 2007. https://doi.org/10.1007/978-1-4020-5514-0_38
[21] Wang Y, Holden JM, Bi XX, Eklund PC. Thermal decomposition of polymeric C60. Chem Phys Lett 1994; 217: 413-7. https://doi.org/10.1016/0009-2614(93)E1409-A
[22] Eklund PC, Rao AM, Zhou P, Wang Y, Holden JM. Photochemical transformation of C60 and C70 films. Thin Sol Films 1995; 257: 185-203. https://doi.org/10.1016/0040-6090(94)05704-4
[23] Pusztai T, Oszlanyi G, Faigel G, et al. Bulk structure of phototransformed C60. Sol St Commun 1999; 111: 595-9. https://doi.org/10.1016/S0038-1098(99)00267-7
[24] Zaginaichenko S Yu, Matysina ZA, Schur DV. The statistical theory of photo- and electropolymerization of fullerenes. Nanosystems, Nanomaterials, Nanotechnologies 2012; 10: 731-45 (in Russ.).
Downloads
Published
How to Cite
Issue
Section
License
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .