Refractrometic Studies of Binary Mixtures of Flavoured Compounds and Some Hydrocarbons
DOI:
https://doi.org/10.6000/1929-5030.2013.02.01.8Keywords:
Refractive index, binary liquid mixtures and molar refraction, densityAbstract
Refractive indices have been measured for the binary liquid mixtures of n-butylethanoate and 3- methylethanoate with cyclohexane, benzene, 1,4-dimethylbenzene and 1,3,5-trimethylbenzene over the entire composition range at 308.15K . From the experimental data, the values of deviation in refractive index (Δn), molar refraction (R) and deviation in molar refraction (ΔR) have been determined. The values of Δn and ΔR have been fitted to the Redlich Kister polynomial equation to determine the standard deviation.
References
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[14] Marchetti AL, Tassi L, Ulrici A, Vaccari G, Sanna G. Refractive indices of binary mixtures of (1,2-dichloroethane + 2-chloroethanol) at various temperatures. J Chem Thermodyn 1999; 31: 647. http://dx.doi.org/10.1006/jcht.1998.0475
[15] Aralaguppi MI, Amniabhavi TM, Balundgi RH, Joshi SS. Thermodynamic interactions in mixtures of bromoform with hydrocarbons. J Phys Chem 1991; 5299. http://dx.doi.org/10.1021/j100166a070
[16] Amniabhavi TM, Aralaguppi MI, Harogoppad SB, Balundgi RH. Densities, viscosities, refractive indices, and speeds of sound for methyl acetoacetate + aliphatic alcohols (C1-C8). J Chem Eng Data 1993; 38: 31. http://dx.doi.org/10.1021/je00009a008
[2] Baragi JG, Aralaguppi MI, Aminabhavi TM. Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of Anisole with 2-Chloroethanol, 1,4-Dioxane, Tetrachloroethylene, Tetrachloroethane, DMF, DMSO, and Diethyl Oxalate at (298.15, 303.15, and 308.15) K. J Chem Eng Data 2005; 50: 910-16. http://dx.doi.org/10.1021/je049610v
[3] Diwedi A, Singh M. Densities, viscosities, viscosity deviations and excess thermodynamic properties of binary liquid mixtures of diethyl oxalate and dimethyl malonate with polar and non-polar solvents at 303.15 K. Indian J Chem 2007; 46A: 789-94.
[4] Nikam PS, Kharat SJ. Density and Viscosity Studies of binary Mixtures of N,N-Dimethylformamide with Toluene and Methyl Benzoate at (298.15, 303.15, 308.15, and 313.15) K. J Chem Eng Data 2005; 50: 455-59. http://dx.doi.org/10.1021/je040012q
[5] Lien PJ, Wu ST, Lee MJ, Lin HM. Excess Molar Enthalpies for Dimethyl Carbonate with o-Xylene, m-Xylene, p-Xylene, Ethylbenzene, or Ethyl Benzoate at 298.15 K and 10.2 MPa. J Chem Eng Data 2003; 48: 632-36. http://dx.doi.org/10.1021/je020181f
[6] Lien PJ, Lin HM, Lee MJ, Venkatesu P. Excess molar enthalpies of diethyl carbonate with o-xylene, m-xylene, pxylene, ethylbenzene, or ethyl benzoate at 298.15 K. Fluid Phase Equilib 2003; 206: 105-15. http://dx.doi.org/10.1016/S0378-3812(02)00308-4
[7] Garcia B, Alcalde R, Aparicio S, Leal JM. Thermophysical Behavior of Methylbenzoate + n-Alkanes Mixed Solvents. Application of Cubic Equations of State and Viscosity Models. Phys Chem Chem Phys 2002; 4: 5833-40.
[8] Garcia B, Alcalde R, Aparicio S, Leal JM. Thermophysical Behavior of Methylbenzoate + n-Alkanes Mixed Solvents. Application of Cubic Equations of State and Viscosity Models. Ind Eng Chem Res 2002; 41: 4399-408. http://dx.doi.org/10.1021/ie020008c
[9] Lange NA. Hand Book of Chemistry. 10th ed., Mc. Graw – Hill Company, New Yark 1996.
[10] Levitt BP. Findlay’s Practical Chemistry. 9th ed., Longman Group Limited, London 1973.
[11] Redlich O, Kister AT. Thermodynamics of Nonelectrolyte Solutions-x-y-t Relations in a Binary System. Ind Eng Chem 1948; 40: 341. http://dx.doi.org/10.1021/ie50458a035
[12] Desnoyers JE, Perron G. Treatment of excess thermodynamic quantities for liquid mixtures. J Sol Chem 1997; 26: 749. http://dx.doi.org/10.1007/BF02767781
[13] Tojo J, Diaz C. Densities and Refractive Indices for 1-Hexane + o-Xylene, m-Xylene,+ p-Xylene, and +Ethylbenzene. J Chem Eng Data 1995; 40: 96-98. http://dx.doi.org/10.1021/je00017a021
[14] Marchetti AL, Tassi L, Ulrici A, Vaccari G, Sanna G. Refractive indices of binary mixtures of (1,2-dichloroethane + 2-chloroethanol) at various temperatures. J Chem Thermodyn 1999; 31: 647. http://dx.doi.org/10.1006/jcht.1998.0475
[15] Aralaguppi MI, Amniabhavi TM, Balundgi RH, Joshi SS. Thermodynamic interactions in mixtures of bromoform with hydrocarbons. J Phys Chem 1991; 5299. http://dx.doi.org/10.1021/j100166a070
[16] Amniabhavi TM, Aralaguppi MI, Harogoppad SB, Balundgi RH. Densities, viscosities, refractive indices, and speeds of sound for methyl acetoacetate + aliphatic alcohols (C1-C8). J Chem Eng Data 1993; 38: 31. http://dx.doi.org/10.1021/je00009a008
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Published
2013-03-01
How to Cite
Yadav, N., Arfin, T., & Yadav, S. S. (2013). Refractrometic Studies of Binary Mixtures of Flavoured Compounds and Some Hydrocarbons. Journal of Applied Solution Chemistry and Modeling, 2(1), 68–76. https://doi.org/10.6000/1929-5030.2013.02.01.8
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