Influence of Low-Frequency Sonolysis on the Kinetics of Liquid-Phase Chemical Reactions Involving Associates

Authors

  • Tatiana P. Kulagina Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow, 142432, Russia
  • Lev P. Smirnov Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow, 142432, Russia
  • Zoya S. Andrianova Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow, 142432, Russia

Keywords:

Chemical reaction, Kinetics, Liquid medium, Reagent association, Low-frequency action.

Abstract

The influence of low-frequency sonolysis on the kinetics of liquid-phase bimolecular liquid-phase reactions was studied by mathematical modeling with due regard for the association of starting reagents into dimers and trimers. With increasing frequency and amplitude of low-frequency sonic waves (up to some critical value), we observed the disappearance of trimers and concomitant cessation of the reaction. This observation offers an additional tool for controlling reaction rate by the external action of low-frequency vibrations.

References

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Published

2018-12-14

How to Cite

Kulagina, T. P. ., Smirnov, L. P. ., & Andrianova, Z. S. . (2018). Influence of Low-Frequency Sonolysis on the Kinetics of Liquid-Phase Chemical Reactions Involving Associates. Journal of Applied Solution Chemistry and Modeling, 7, 52–54. Retrieved from https://mail.lifescienceglobal.com/pms/index.php/JASCM/article/view/7757

Issue

Vol. 7 (2018)

Section

General Articles

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