Transport of Ions and Solvent Through a Nafion Membrane Modified with Polypyrrole
DOI:
https://doi.org/10.6000/1929-6037.2012.01.02.5Keywords:
Polymerisation, Polypyrrole, Transport, Metal Cation, Methanol, Nafion®Abstract
The Nafion®117 membrane was modified chemically, using a conducting polymer pyrrole. The oxidants ferric chloride (PPy-Fe), hydrogen peroxide (PPy-O) and ammonium persulfate (PPy-S) were used to carry out the polymerization in the membrane both in aqueous and organic media. The Nafion® modified in the presence of the N-méthylformamide increases the transport of alkali and heavy metal cations and reduces considerably the transport of methanol both in diffusion and electro-osmosis. Therefore, the modified Nafion® membrane can be used successfully in electrodialysis of electrolyte solutions in both aqueous and hydro-organic media and may be regarded as a good material to use in Direct Methanol Fuel Cells.
References
Easton EB, Langsdorf BL, Hughes JA, Sultan J, Qi Z, Kaufman A, Pickup PG. J Electrochem Soc 2003; 150: C735–C739. http://dx.doi.org/10.1149/1.1608005 DOI: https://doi.org/10.1149/1.1608005
Langsdorf BL, Maclean BJ, Halfyard JE, Hughes JA, Pickup PG. J Phys Chem B 2003; 107: 2480–2484.http://dx.doi.org/10.1021/jp026840c DOI: https://doi.org/10.1021/jp026840c
Alberti G, Casciola M. Annu Rev Mater Res 2003; 33: 129–154.http://dx.doi.org/10.1146/annurev.matsci.33.022702.154702 DOI: https://doi.org/10.1146/annurev.matsci.33.022702.154702
Chang CM., Huang HJ. Anal Chim Acta 1995; 300: 15–23.http://dx.doi.org/10.1016/0003-2670(94)00379-Z DOI: https://doi.org/10.1016/0003-2670(94)00379-Z
Partridge AC, Milestone CB, Too CO, Wallace GG. J Memb Sci 1999; 152: 61.http://dx.doi.org/10.1016/S0376-7388(98)00193-8 DOI: https://doi.org/10.1016/S0376-7388(98)00193-8
Ariza MJ, Otero TF. Colloids Surf. A: Physicochem. Eng. Aspects 2005; 226: 270–271 DOI: https://doi.org/10.1016/j.colsurfa.2005.06.006
Zachara JE, Toczyłowska R, Pokrop R, Zagorska M, Dybko A, Wroblewski W. Sens. Actuators B 2004; 101: 207–212.http://dx.doi.org/10.1016/j.snb.2004.02.052 DOI: https://doi.org/10.1016/j.snb.2004.02.052
Wang L-X, Li X-G., Yang Y-L. React Funct Polym 2001; 47: 125–139.http://dx.doi.org/10.1016/S1381-5148(00)00079-1 DOI: https://doi.org/10.1016/S1381-5148(00)00079-1
Burgmayer P, Murray RW. J Am Chem Soc 1982; 104: 6139–6140.http://dx.doi.org/10.1021/ja00386a061 DOI: https://doi.org/10.1021/ja00386a061
Partridge AC, Milestone C, Too CO, Wallace GG. J Memb Sci 1997; 132: 245.http://dx.doi.org/10.1016/S0376-7388(97)00072-0 DOI: https://doi.org/10.1016/S0376-7388(97)00072-0
Zhao H, Price WE, Wallace GG. Polymer 1993; 34: 16–20.http://dx.doi.org/10.1016/0032-3861(93)90276-G DOI: https://doi.org/10.1016/0032-3861(93)90276-G
Sata T, Ogura S, Kiskimoto F. J Memb Sci 1993; 84: 259–269.http://dx.doi.org/10.1016/0376-7388(93)80021-O DOI: https://doi.org/10.1016/0376-7388(93)80021-O
Xu F, Innocent C, Bonnet B, Jones DJ, Rosiere J. Fuel Cells 2005; 5: 398-405.http://dx.doi.org/10.1002/fuce.200400077 DOI: https://doi.org/10.1002/fuce.200400077
Kameche M, Xu F, Innocent C, Pourcelly G, Derriche Z. Desalination 2004; 168: 319-327.http://dx.doi.org/10.1016/j.desal.2004.07.015
Kameche M, Xu F, Innocent C, Pourcelly G. Desalination 2003; 153: 9-15.http://dx.doi.org/10.1016/S0011-9164(03)00203-0 DOI: https://doi.org/10.1016/S0011-9164(03)00203-0
Innocent C, Huguet P, Kameche M, Bribes JL, Pourcelly G. Phys Chem Chem Phys 2001; 3: 1481-1485.http://dx.doi.org/10.1039/b008318f DOI: https://doi.org/10.1039/b008318f
Kameche M, Innocent C, Xu F, Pourcelly G, Derriche Z. Desalination 2004; 168: 319-327.http://dx.doi.org/10.1016/j.desal.2004.07.015 DOI: https://doi.org/10.1016/j.desal.2004.07.015
Xu F, Innocent C, Pourcelly G. Sep Pur Technol 2005; 43: 17-24.http://dx.doi.org/10.1016/j.seppur.2004.09.009 DOI: https://doi.org/10.1016/j.seppur.2004.09.009
Chaabane L, Innocent C, Bulvestre G, Pourcelly G, Auclair B. Eur Polym J 2006; 42: 14036-1416.http://dx.doi.org/10.1016/j.eurpolymj.2005.12.019 DOI: https://doi.org/10.1016/j.eurpolymj.2005.12.019
Tian B, Zerbi G. J Chem Phys 1990; 92: 3892-3898http://dx.doi.org/10.1063/1.457795 DOI: https://doi.org/10.1063/1.457795
Hong L, Zhou Y, Chen N, Li K. J Colloid Interface Sci 1999; 218: 233-242http://dx.doi.org/10.1006/jcis.1999.6385 DOI: https://doi.org/10.1006/jcis.1999.6385
Jia N, Lefebvre MC, Hafyrad J, Qi Z, Pickup PG. Electrochem Solid State Letter, 2000;3: 529-531. http://dx.doi.org/10.1149/1.1391199 DOI: https://doi.org/10.1149/1.1391199
Sungpet A. J Memb Sci 2003; 226: 131-134.http://dx.doi.org/10.1016/j.memsci.2003.08.015 DOI: https://doi.org/10.1016/j.memsci.2003.08.015
Downloads
Published
How to Cite
Issue
Section
License
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .