Effect of MAX Phase Mo2TiAlC2 on the PVDF Ultrafiltration Membrane Properties and Performance
DOI:
https://doi.org/10.6000/1929-5995.2025.14.17Keywords:
Hydrophilicity, MAX phase Mo2TiAlC2, ultrafiltration, PVDF, membraneAbstract
Ultrafiltration membranes are widely used in wastewater filtration due to their efficiency relative to conventional water treatment technologies. To improve the antifouling property of the PVDF membrane, a composite ultrafiltration membrane was fabricated employing the in-situ embedment approach throughout the phase inversion process and utilizing a new 2D material, MAX phase Molybdenum Titanium Aluminium Carbide (Mo2TiAlC2). The membranes were described using Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), and porosity measurements. Rejection tests were applied to study the produced membranes. Adding Mo2TiAlC2 increased the hydrophilicity of the composite membrane compared to the pristine membrane. Porosity and membrane pore size increased with the addition up to 0.6% wt. The most hydrophilic membrane (M3) recorded the highest protein rejection of 84.9%, which was much higher than that of the pristine membrane. These findings highlight the potential of Mo2TiAlC2 as a promising PVDF membrane additive.
References
Tijana Uroˇsevic and Katarina Trivunac. Achievements in low-pressure membrane processes microfiltration (MF) and ultrafiltration (UF) for wastewater and water treatment. In Current Trends and Future Developments on (Bio-) Membranes. Elsevier 2020; pp. 67-107. DOI: https://doi.org/10.1016/B978-0-12-817378-7.00003-3
Inamuddin RB, Asiri AM. Self-Standing Substrates: Materials and Applications. Engineering Materials. Springer International Publishing, Cham 2020. DOI: https://doi.org/10.1007/978-3-030-29522-6
Aryanti PTP, Hakim AN, Widodo S, Widiasa IN, Wenten IG. Prospect and Challenges of Tight Ultrafiltration Membrane in Drinking Water Treatment. IOP Conference Series: Materials Science and Engineering 2018; 395: 012012. DOI: https://doi.org/10.1088/1757-899X/395/1/012012
Futselaar H, Schonewille H, van Dalfsen H. Ultrafiltration technology for potable, process and waste water treatment. Membrane Science and Technology/Membrane Science and Technology Series 2003.
Universiti Pendidikan Sultan Idris, R. Mohamat, A. B. Suriani, Universiti Pendidikan Sultan Idris, A. Mohamed, Universiti Pendidikan Sultan Idris, Muqoyyanah, Universiti Pendidikan Sultan Idris, M. H. D. Othman, Universiti Teknologi Malaysia, R. Rohani, Universiti Kebangsaan Malaysia, M. H. Mamat, Universiti Teknologi MARA (UiTM), M. K. Ahmad, Universiti Tun Hussein Onn Malaysia, M. F. Malek, Universiti Teknologi MARA (UiTM), H. P. S. Abdul Khalil, Universiti Sains Malaysia, K. Ali, and University of Agriculture Faisalabad. Recent Advances for Wastewater Treatment on Polyvinylidene Fluoride-Based Membrane: A Review. International Journal of Integrated Engineering 2024; 16(5). DOI: https://doi.org/10.30880/ijie.2024.16.05.039
Zou D, Lee YM. Design strategy of poly(vinylidene fluoride) membranes for water treatment. Progress in Polymer Science 2022. DOI: https://doi.org/10.1016/j.progpolymsci.2022.101535
Herlambang Abriyanto. Hydrophilic Modification of PVDF Membrane: A Review.
Improving the hydrophilicity and antifouling performance of PVDF membranes via PEI amination and further poly (methyl vinyl ether-alt-maleic anhydride) modification. Reactive and Functional Polymers 2023; 189: 105610. DOI: https://doi.org/10.1016/j.reactfunctpolym.2023.105610
Khulbe KC, Matsuura T. Membrane Modification. Springer International Publishing 2021; 135-170. DOI: https://doi.org/10.1007/978-3-030-64183-2_4
Van Der Bruggen B. Chemical modification of polyethersulfone nanofiltration membranes: A review. Journal of Applied Polymer Science 2009; 114(1): 630-642. DOI: https://doi.org/10.1002/app.30578
Saffarimiandoab F, Gul BY, Tasdemir RS, Ilter SE, Unal S, Tunaboylu B, Menceloglu YZ, Koyuncu I. A review on membrane fouling: Membrane modification. Desalination and Water Treatment 2021; 216: 47-70. DOI: https://doi.org/10.5004/dwt.2021.26815
Miller DJ, Dreyer DR, Bielawski CW, Paul DR, Freeman BD. Surface Modification of Water Purification Membranes. Angewandte Chemie International Edition 2017; 56(17): 4662-4711. DOI: https://doi.org/10.1002/anie.201601509
Zhou A, Liu Y, Li S, Wang X, Ying G, Xia Q, Zhang P. From structural ceramics to 2D materials with multi-applications: A review on the development from MAX phases to MXenes. Journal of Advanced Ceramics 2021; 10(6): 1194-1242. DOI: https://doi.org/10.1007/s40145-021-0535-5
Bakardjieva S, Klie R. The Morphology of TiiAlC (M2AX) and TiiC (MXene) Sheets Revealed by HAADF STEM Analysis. Microscopy and Microanalysis 2018; 24(S1): 156-157. DOI: https://doi.org/10.1017/S1431927618001277
Luxa J, Kupka P, Fedor Lipilin, Jiˇrı S, Subramani A, Lazar P, Sofer Z. Hydrogen Evolution Reaction Activity in Mo2TiC2 Tx MXene Derived from Mo2 TiAlC2 MAX Phase: Insights from Compositional Transformations. ACS Catalysis 2024; 14(20): 15336-15347. DOI: https://doi.org/10.1021/acscatal.4c04099
Ali MS, Rayhan MA, Ali MA, Parvin R, Islam AKMA. New MAX Phase Compound Mo2TiAlC2: First-principles Study. Journal of Scientific Research 2016; 8(2): 109-117. DOI: https://doi.org/10.3329/jsr.v8i2.25057
Zhang J, Xu Z, Mai W, Min C, Zhou B, Shan M, Li Y, Yang C, Wang Z, Qian X. Improved hydrophilicity, permeability, antifouling and mechanical performance of PVDF composite ultrafiltration membranes tailored by oxidized low-dimensional carbon nanomaterials. Journal of Materials Chemistry A 2013; 1(9): 3101. DOI: https://doi.org/10.1039/c2ta01415g
Ayyaru S, Dinh TTL, Ahn Y-H. Enhanced antifouling performance of PVDF ultrafiltration membrane by blending zinc oxide with support of graphene oxide nanoparticle. Chemosphere 2020; 241: 125068. DOI: https://doi.org/10.1016/j.chemosphere.2019.125068
Ma C, Hu J, Sun W, Ma Z, Yang W, Wang L, Ran Z, Zhao B, Zhang Z, Zhang H. Graphene oxide-polyethylene glycol incorporated PVDF nanocomposite ultrafiltration membrane with enhanced hydrophilicity, permeability, and antifouling performance. Chemosphere 2020; 253: 126649. DOI: https://doi.org/10.1016/j.chemosphere.2020.126649
Ostovar A, Tarkhani M, Mousavi SA, Asadollahi M. Surface modification of GO/PVDF composite membrane by MXene/protonated g-C3N4 nanosheets hybrids with improved dye separation and antifouling properties. Polymer Engineering & Science 2024. DOI: https://doi.org/10.1002/pen.26566
Abood TW, Shabeeb KM, Alzubaydi AB, Sh. Majdi H, Al-Juboori RA, Alsalhy QF. Effect of MAX Phase Ti3ALC2 on the Ultrafiltration Membrane Properties and Performance. Membranes 2023; 13(5): 456. DOI: https://doi.org/10.3390/membranes13050456
Abood T, Shabeeb K, Alzubaydi A, Goh P, Ismail A, Zrelli A, Alsalhy Q. Effect of MXene Ti3C2 on the PVDF ultrafiltration membrane properties and performance. Engineering and Technology Journal 2024; 0(0): 1-14. DOI: https://doi.org/10.30684/etj.2024.145778.1663
Hou L, Zhang J, Zhang X, Wu Z, Wang Q. Enhancement of PVDF membrane anti-fouling ability based on critical flux: Effects of fabrication parameters and membrane properties. Desalination and Water Treatment 2025; 321: 101061. DOI: https://doi.org/10.1016/j.dwt.2025.101061
Zhang W, Fu C, Low J, Duan D, Ma J, Jiang W, Chen Y, Liu H, Qi Z, Long R, Yao Y, Li X, Zhang H, Liu Z, Yang J, Zou Z, Xiong Y. High-performance photocatalytic nonoxidative conversion of methane to ethane and hydrogen by heteroatoms-engineered TiO2. Nature Communications 2022; 13(1): 2806. DOI: https://doi.org/10.1038/s41467-022-30532-z
Khivantsev K, Biancardi A, Fathizadeh M, Almalki F, Grant JL, Tien HN, Shakouri A, Blom DA, Makris TM, Regalbuto JR, Caricato M, Yu M. Catalytic N-H Bond Activation and Breaking by a Well-Defined CoII1O4 Site of a Heterogeneous Catalyst. ChemCatChem 2018; 10(4): 736-742. DOI: https://doi.org/10.1002/cctc.201701268
Downloads
Published
How to Cite
Issue
Section
License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .