Comparative Degradation of LDPE, HDPE and HMHDPE under Different Soil Conditions
DOI:
https://doi.org/10.6000/1929-5995.2014.03.03.5Keywords:
Polyethylene, Environment, Polymer, Black soil, DegradationAbstract
The Present work includes, degradation of polyethylene under different environmental conditions to know the effect of physical, chemical and biological factors prevailing in those conditions on degradation of polyethylene. Plastic films viz., Low density polyethylene (LDPE), High density polyethylene (HDPE) and High molecular weight high density polyethylene (HMHDPE) each were incubated in three different conditions viz., black soil, sandy soil and red soil for a period of 3 months. The changes in the properties of plastic films after incubation was studied by change in the weight of the plastic film and mechanical parameters like tensile strength, breaking load and percentage of elongation. Among all the plastic films HDPE was found to be highly susceptible with 33% weight loss and 40% reduction in percentage of elongation compared to LDPE with 26% weight loss and 34 % reduction in percentage of elongation in black soil. Whereas HMHDPE found to be highly resistant in all the soils with no significant weight loss and percentage of elongation (15%). None of the plastic films had shown degradation in sandy soil even after incubation for 3 months. FTIR spectroscopy results showed that HDPE film incubated in black soil had undergone extensive degradation when compared with un incubated HDPE film.
References
Dilara PA, Briassoulis D. Degradation. J Agric Eng Res 2000; 76: 309-21. http://dx.doi.org/10.1006/jaer.1999.0513 DOI: https://doi.org/10.1006/jaer.1999.0513
Swift G. Non-medical biodegradable polymers: Environmentally degradable polymers. In: Domb AJ, Kost J,Wiseman DM, editors. Handbook of Biodegradable Polymers. Amsterdam: Harwood Academic Press 1997; p. 473-511. DOI: https://doi.org/10.1201/9781420049367.ch23
Gopferich A, Mechanisms of polymer degradation and elimination. In:Domb AJ, Kost J,Wiseman DM, editors. Handbook of Biodegradable Polymers. Amsterdam: Harwood Academic Press 1997; p. 451-71.
Kamal MR, Haung B. Natural and artificial weathering of polymers. In: Hamid SH, Ami MB,Maadhan AG, editors. Handbook of Polymer Degradation. New York: Marcel Dekker 1992; p. 127-168.
Griffin GJL. Synthetic. Pure Appl Chem 1980; 52: p. 399-407. DOI: https://doi.org/10.1351/pac198052020399
Paszczynski AV, Huynh B, Crawford R. Enzymatic. FEMS Microbiol Lett 1985; 29: 37-41. DOI: https://doi.org/10.1111/j.1574-6968.1985.tb00831.x
Tuisel HR, Sinclair JA, Bumpus W, Ashbaugh B, Brock J, Aust SD. Lignin. Arch Biochem Biophys1990; 279: 158-66. http://dx.doi.org/10.1016/0003-9861(90)90476-F DOI: https://doi.org/10.1016/0003-9861(90)90476-F
Alexander M. Soil Microbiology. 2nd ed. John Wiley and Sons: New York; 1977.
Green F, Highley TL. Mechanism. Int Biodeter Biodegr 1997; 39: 113-24. http://dx.doi.org/10.1016/S0964-8305(96)00063-7 DOI: https://doi.org/10.1016/S0964-8305(96)00063-7
Mengel K, Kirkby EA. Principles of Plant Nutrition. 3rd ed. International Potash Institute, Worblaufen-Bern: Switzerland; 1982.
Toncheva V, Bulcke AVD, Schacht E, Mergaert J, Swings J Synthesis J Env Polym Degrad 1996; 4: 71-83. http://dx.doi.org/10.1007/BF02074868 DOI: https://doi.org/10.1007/BF02074868
Jun HS, Kim BO, Kim YC, Chang HN, Woo SI. Synthesis. J Env Polym Degrad 1994; 2: 9-18. http://dx.doi.org/10.1007/BF02073482 DOI: https://doi.org/10.1007/BF02073482
Goldberg D. A review. J Env Polym Degrad 1995; 3: 61-8. http://dx.doi.org/10.1007/BF02067481 DOI: https://doi.org/10.1007/BF02067481
Winursito I, Matsumura S. Biodegradability. J Env Polym Degrad 1996; 4: 113-21. http://dx.doi.org/10.1007/BF02074872 DOI: https://doi.org/10.1007/BF02074872
Heidary S, Gordon B. Hydrolyzable. J Env Polym Degrad 1994; 2: 19-26. http://dx.doi.org/10.1007/BF02073483 DOI: https://doi.org/10.1007/BF02073483
Hiltunen K, Seppälä JV, Itävaara M, Härkönen M. The biodegradation. J Env Polym Degrad 1997; 5: 167-73.
Singh V, Dubey M, Bhaudaria S. Microbial. Asian J Exp Biol Sci 2012; 3(3): 498-501.
Ibrahim IN, Maraqa A, Hameed KM. Assessment. Turk J Biol 2011; 35: 551-557.
Sepperumal U, Markandan M, Palraja I. Micromorphological. J Microbiol Biotechnol Res 2013; 3(4): 47-53.
Albertsson AC. Degradable. J Macromol Sci Pure Appl Chem 1993; 9-10: 757-65. http://dx.doi.org/10.1080/10601329308021261 DOI: https://doi.org/10.1080/10601329308021261
Day M, Shaw K Cooney D. Watts J, Harrigan B. Degradable. J Env Polym Degrad 1997; 5: 137-151.
Osawa Z. Photo induced degradation of polymers. In: Hamid SH, Ami MB, Maadhan AG, editors. Handbook of Polymer Degradation. New York: Marcel Dekker 1992; 169-217.
Colin G, Cooney JD, Carlsson DJ, Wiles DM. Deterioration. J Appl Polym Sci 1981; 26: 509-19. http://dx.doi.org/10.1002/app.1981.070260211 DOI: https://doi.org/10.1002/app.1981.070260211
Yutaka T, Buenaventurada PC, Charles UU, Seiichi A. Biodegradability. Int J Mol Sci 2009; 10: 3722-42. http://dx.doi.org/10.3390/ijms10093722 DOI: https://doi.org/10.3390/ijms10093722
Tokiwa Y, Ando T, Suzuki T. Degradation. J Ferm Technol 1976; 54: 603-8.
Tokiwa Y, Suzuki T. Hydrolysis. Agric Biol Chem 1978; 42: 1071-2. http://dx.doi.org/10.1271/bbb1961.42.1071 DOI: https://doi.org/10.1080/00021369.1978.10863111
Tokiwa Y, Suzuki T, Ando T. Synthesis. J Appl Polym Sci 1979; 24: 1701-11. http://dx.doi.org/10.1002/app.1979.070240710 DOI: https://doi.org/10.1002/app.1979.070240710
Albertsson AC, Karlsson S. The influence. Prog Polym Sci 1990; 15: 177-92. http://dx.doi.org/10.1016/0079-6700(90)90027-X DOI: https://doi.org/10.1016/0079-6700(90)90027-X
Otake Y, Kobayashi T, Ashabe H, Murukami N, Ono K. Biodegradation. J Appl Polym Sci 1995; 56: 1789-96. http://dx.doi.org/10.1002/app.1995.070561309 DOI: https://doi.org/10.1002/app.1995.070561309
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