Influence of Cobalt (II) Chloride Catalysed on the Thermal and Optical Characterization of PEO Based Solid Polymer Electrolytes

Authors

  • Sharanappa Chapi Department of Physics, Mangalore University, Mangalagangothri – 574 199, India
  • H. Devendrappa Department of Physics, Mangalore University, Mangalagangothri – 574 199, India

DOI:

https://doi.org/10.6000/1929-5995.2014.03.04.2

Keywords:

XRD, Optical band gaps, SEM, Fluorescence, Thermal stability.

Abstract

Solution-casting technique was employed for the preparation of solid polymer electrolyte based polyethylene oxide (PEO) with 0, 1, 3 and 5 weight percentage cobalt chloride (CoCl2) films were characterized by X-ray Diffractometry (XRD), Differrential Scanning Calorimetry (DSC), Scanning Electron Microscope (SEM) and Ultra Violet-Visible (UV-Vis.) Spectroscopy methods. The optical band gaps, absorption band edges and Urbach energy shows decrease with increasing of Co+2 ion concentration in the polymer matrix because of the formation of free radicals or cluster. The Thermogravimetry (TG) and Derivative Thermogravimetry (DTG) were used to examine the thermal stability of the film and it was found that the stability of the complexes is higher than that of the pure PEO due to the addition of CoCl2. The wavelength position of a fluorescence emission band varied by increasing of a dopant wt % of salt.

References

Subba Reddy Ch.V, Sharma AK, Narasimha Rao VVR. Polymer 2009; 47: 1318. DOI: https://doi.org/10.1016/j.polymer.2005.12.052

Ravi M, Kiran Kumar K, Madhu Mohan V, Narasimha Rao VVR. Polymer Testing 2014; 33: 152. http://dx.doi.org/10.1016/j.polymertesting.2013.12.002 DOI: https://doi.org/10.1016/j.polymertesting.2013.12.002

Reddeppa N, Reddy CVS, Achari VBS, Narasimha Rao VVR, Sharma AK. Ionics 2009; 15: 255. http://dx.doi.org/10.1007/s11581-008-0269-1 DOI: https://doi.org/10.1007/s11581-008-0269-1

Turky G, Dawy M. Materials Chemistry and Physics 2002; 77: 48. http://dx.doi.org/10.1016/S0254-0584(01)00574-0 DOI: https://doi.org/10.1016/S0254-0584(01)00574-0

Onoda M, Manada Y, Moritn S, Yoshino K. Journal of Physical Society of Japan 1989; 58: 1985. http://dx.doi.org/10.1143/JPSJ.58.1895 DOI: https://doi.org/10.1143/JPSJ.58.1895

Tabatn M, Satoh M, Kanoto K, Yoshiro K. Journal of Physical Society of Japan 1986; 55: 1305. http://dx.doi.org/10.1143/JPSJ.55.1305 DOI: https://doi.org/10.1143/JPSJ.55.1305

Proneanu S, Toren R, Brie M, Mihilesan G. Materials Science Forum 1995; 191: 241. http://dx.doi.org/10.4028/www.scientific.net/MSF.191.241 DOI: https://doi.org/10.4028/www.scientific.net/MSF.191.241

Sundar M, Selladurri S. Ionics 2006; 12: 281. http://dx.doi.org/10.1007/s11581-006-0048-9 DOI: https://doi.org/10.1007/s11581-006-0048-9

Lee JK, Lee YJ, Chae WS, Sung YM. Journal of Electroceramics 1997; 17: 941. http://dx.doi.org/10.1007/s10832-006-7672-7 DOI: https://doi.org/10.1007/s10832-006-7672-7

Uma Devi C, Sharma AK, Narasimha Rao VVR. Materials Letters 2002; 56: 167. http://dx.doi.org/10.1016/S0167-577X(02)00434-2 DOI: https://doi.org/10.1016/S0167-577X(02)00434-2

Subba Reddy ChV, Sharma AK, Narasimha Rao VVR. Journal of Materials Science Letters 2002; 21: 105. http://dx.doi.org/10.1023/A:1014276611225

Subba Reddy ChV, Sharma AK, Narasimha Rao VVR. Journal of Power Sources 2002; 111: 357. DOI: https://doi.org/10.1016/S0378-7753(02)00040-X

Lakshmi Narayana K. Ph D Thesis, SV University 1995.

Staryga E, Swiatek J. Thin Solid Films 1979; 56: 311. http://dx.doi.org/10.1016/0040-6090(79)90132-9 DOI: https://doi.org/10.1016/0040-6090(79)90132-9

Bahri R, Singh HP. Thin Solid Films 1980; 69: 281. http://dx.doi.org/10.1016/0040-6090(80)90578-7 DOI: https://doi.org/10.1016/0040-6090(80)90578-7

Obreja P, Kusko M, Cristea D, Purica M. Proceeding of the Symposium on Photonics Technologies for Framework Program 2006; 392.

Faim TD. Proceedings of SPIE 2004; 5250: 423. http://dx.doi.org/10.1117/12.513363 DOI: https://doi.org/10.1117/12.513363

Ravi M, Pavani Y, Kiran Kumar K, Bhavani S, Sharma AK, Narasimha Rao VVR. Materials Chemistry and Physics 2011; 130: 442. http://dx.doi.org/10.1016/j.matchemphys.2011.07.006 DOI: https://doi.org/10.1016/j.matchemphys.2011.07.006

Ulanski J, Polanowski P, Traiez A, Hofmann M, Dormann E. Synthetic Metals 1998; 94: 23. http://dx.doi.org/10.1016/S0379-6779(97)04133-7 DOI: https://doi.org/10.1016/S0379-6779(97)04133-7

Subramanya K, Raghu S, Devendrappa H. AIP Conf Proc 2012; 1447: 965.

Saumya RM, Awalendra K, Thakur, Chaudhary RNP. Ionics 2008; 14: 255. DOI: https://doi.org/10.1007/s11581-007-0171-2

Katharina M, Picker-Freyer. Journal of Thermal Analysis and Calorimetry 2006; 85(2): 495. DOI: https://doi.org/10.1007/s10973-006-7698-8

Reddy MJ, Chu PP. Electrchim Acta 2002; 47: 1189. http://dx.doi.org/10.1016/S0013-4686(01)00846-5 DOI: https://doi.org/10.1016/S0013-4686(01)00846-5

Halder B, Singru RM, Maurya KK, Chandra S. Phys Rev B 1996; 54: 7143. http://dx.doi.org/10.1103/PhysRevB.54.7143 DOI: https://doi.org/10.1103/PhysRevB.54.7143

Al-Faleh RS, Zihlif AM. Physica B 2011; 406: 1919. http://dx.doi.org/10.1016/j.physb.2011.01.076 DOI: https://doi.org/10.1016/j.physb.2011.01.076

Suriani Ibrahim, Roslina Ahmad. Journal of Luminescence 2012; 132: 147. http://dx.doi.org/10.1016/j.jlumin.2011.08.004 DOI: https://doi.org/10.1016/j.jlumin.2011.08.004

Zajak H. Optics, Addison Wesley, London 1975; 85.

Elliot S. The Physics Chemistry of Solids, John Wiley, New York 1998; 225: 392.

Abu-Jamous A, Zihlif AM. Physica B 2010; 405: 2762. http://dx.doi.org/10.1016/j.physb.2010.02.050 DOI: https://doi.org/10.1016/j.physb.2010.02.050

Davis E, Mott N. Philos Mag 1970; 22: 179. http://dx.doi.org/10.1080/14786437008221061 DOI: https://doi.org/10.1080/14786437008221061

Davis DS, Shalliday JS. Phys Rev 1960; 118: 1020. http://dx.doi.org/10.1103/PhysRev.118.1020 DOI: https://doi.org/10.1103/PhysRev.118.1020

Thutulpalli GM, Tomlin SG. J Phys D: Appl Phys 1976; 9: 1639. http://dx.doi.org/10.1088/0022-3727/9/11/010 DOI: https://doi.org/10.1088/0022-3727/9/11/010

Subba Reddy ChV, Sharma AK, Narasimha Rao VVR. Journal of Materials Science Letters 2002; 21: 105. http://dx.doi.org/10.1023/A:1014276611225 DOI: https://doi.org/10.1023/A:1014276611225

Urbach F. Phys Rev 1953; 92: 1324. http://dx.doi.org/10.1103/PhysRev.92.1324 DOI: https://doi.org/10.1103/PhysRev.92.1324

Zidan HM, Abu-Elnader M. Physica B 200; 355: 308. DOI: https://doi.org/10.1016/j.physb.2004.11.023

Raja V, Sharma AK, Narasimha Rao VVR. Mater Lett 2003; 57: 4678. http://dx.doi.org/10.1016/S0167-577X(03)00384-7 DOI: https://doi.org/10.1016/S0167-577X(03)00384-7

Phukan T, Kanjilal D, Goswami TD, Das HL. Radiat Meas B 2003; 36: 611. DOI: https://doi.org/10.1016/S1350-4487(03)00210-5

Abdul-Kader AM, Turos A, Jagielski J, Nowicki L, Ratajczak R, Stonert A, Al-Madeed M. 2005; 78: 281. DOI: https://doi.org/10.1016/j.vacuum.2005.01.039

Vijay Kumar, Sonkawade RG. Radiation Physics and Chemistry 2012; 81: 652. http://dx.doi.org/10.1016/j.radphyschem.2012.02.027 DOI: https://doi.org/10.1016/j.radphyschem.2012.02.027

Braun W, Hellwege KH, Knappe W, Kolid-Z UZ. Polymer 1967; 215: 10. DOI: https://doi.org/10.1007/BF01500473

Abdelaziz M. Physica B 2011; 406: 1300. http://dx.doi.org/10.1016/j.physb.2011.01.021 DOI: https://doi.org/10.1016/j.physb.2011.01.021

Suriani Ibrahim, Mohd Rafie Johan. Int J Electrochem Sci 2012; 7: 2596.

Wang SG, He H, Cui X J, Gong J, Qu LY. Acta Chimica 2001; 59(8): 1163.

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Published

2015-01-02

How to Cite

Chapi, S., & Devendrappa, H. (2015). Influence of Cobalt (II) Chloride Catalysed on the Thermal and Optical Characterization of PEO Based Solid Polymer Electrolytes. Journal of Research Updates in Polymer Science, 3(4), 205–215. https://doi.org/10.6000/1929-5995.2014.03.04.2

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