Dehydrogenation Catalyst for Organic Hydride on the Basis of Superheated Liquid-Film Concept
DOI:
https://doi.org/10.6000/1929-6002.2016.05.04.1Keywords:
Dehydrogenation catalyst, Organic hydride, Superheated liquid-film.Abstract
Reversible reaction couples of hydrogenation and dehydrogenation of organic compounds e.g. methylcyclohexane and toluene, or 2-propanol and acetone, are described in terms of hydrogen supplier to fuel cells, which will satisfy our demands of combined heat and power at various compact sizes. Carbon supported nano-sized metal particles, wetted with the liquid substrate in a reactor, was used for conversion of organic hydrides into hydrogen and organic compounds, being separable by distillation. Vigorous nucleate boiling is important for heat transfer as well as for irreversible bubble evolution, leading hydrogen to the vapor phase. Once the bubble is broken at the interface, catalytic hydrogenation will be prohibited, because gaseous hydrogen is unable to dissolve into the boiling liquid. Catalytic dehydrogenation under superheated liquid-film conditions can thus convert low-quality heats into hydrogen energy.
References
[1]Gupta RB. Hydrogen Fuel-Storage, Transport and Utilization, CRC Press, New York 2008; Chapt. 1 & 13
[2]Aihara T. Heat Transfer Engineering, Shokabo Press. Tokyo, 1994; Chapt. 5.3.5. “Enforced Fluid Boiling”.
[3]Shono A, Saito Y. Technology Assembly for Utilization of Hydrogen. NTS Press, 2014; Chapt. 2.6.1. “Organic Hydride for Storage & Transport System of Hydrogen”.
[4]Saito Y. Engineering System for Fine Particles – Applied Technology II (Ed. H. Yanagida), Fuji Techno-system Press, Tokyo 2002; Chapt. 9.2.2. “Metal Fine Particle Catalyst”.
[5]Hodoshima S, Takaiwa S, Shono A, Satoh K, Saito Y. Appl Catal A: General 2005; 283: 235-242.https://doi.org/10.1016/j.apcata.2005.01.010
[6]Glansdorff G, Prigogine I. Thermodynamic Theory of Structure, Stability and Fluctuations, Wiley, London 1971; Chapt. 3.
[7]Hodoshima S, Shono A, Saito K, Saito Y. Stud Surf Sci Catal 2006; 159: 177-180.https://doi.org/10.1016/S0167-2991(06)81562-4
[8]Shono A, Hashimoto T, Hodoshima S, Satoh K, Saito Y. J Chem Eng Jpn 2006; 39: 211-215.https://doi.org/10.1252/jcej.39.211
[9]Hodoshima S, Shono A, Saito Y. Energy Fuels 2008; 22: 2559-2569.https://doi.org/10.1021/ef700607h
[10]Saito Y, Aramaki K, Hodoshima S, Saito M, Shono A, Kuwano J, Otake K. Chem Eng Sci 2008; 63: 4935-4941.https://doi.org/10.1016/j.ces.2007.11.036
[11]Okada Y. Energy Catalyst Technology, Muroi T, Ed. Science & Technology Press, Tokyo, “Catalyst Technology for Hydrogen Storage and Transport System with Use of Organic Hydride” 2010; Chapt. 7.2.
[12]NEDO, White Paper on Hydrogen Energy. Nikkan Kogyo Newspaper Press, “Domestic, Business & Industrial Use of Fuel Cell” 2015; Chapt. 6.5.1-2.
[13]Saito Y, Okada Y. Energy Technology Roadmap of Japan: Future Energy Systems Based on Feasible Technologies Beyond 2030, Kato Y, Koyama M, Nakagaki T, Eds., Springer, London, Topics in Primary and Secondary Sectors of Industry, “Organic Hydride for Hydrogen Energy Carrier” 2016; Chapt. 6
Downloads
Published
How to Cite
Issue
Section
License
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .
