Production and Characterization of Bio-Chars and Bio-Oils Formed by Pyrolysis of Persian Hogweed (Heracleum persicum Desf.) in A Fixed-Bed Reactor

Authors

  • Tevfik Aysu Yuzuncu Yil University

DOI:

https://doi.org/10.6000/1929-5030.2013.02.04.1

Keywords:

Energy, Biomass, Pyrolysis, Bio-oil, Persian Hogweed, Heracleum persicum Desf

Abstract

Pyrolysis of Persian Hogweed (Heracleum persicum Desf.) stalks were performed in a fixed-bed tubular reactor with (K2CO3, ZnCl2) and without catalyst at three different temperatures (400, 500 and 600 oC) with a constant heating rate of 50 oC/min. and with a constant sweeping gas (N2) flow rate of 100 cm3/min. The amounts of bio-char, bio-oil and gas produced were calculated and the compositions of the obtained bio-oils were characterized by GC-MS. The effects of pyrolysis parameters such as temperature and catalyst on the product yields were investigated. According to the results, both temperature and catalyst had significant effects on the conversion of Heracleum persicum Desf. into bio-chars, bio-oils and gaseous products. The highest bio-oil yield of 41.42% by weight including aqeous phase was achieved with 10% potassium carbonate catalyst at 500 oC. 71 different compounds were identified by GC-MS in the bio-oils obtained at 500 oC.

Author Biography

Tevfik Aysu, Yuzuncu Yil University

Department of Chemistry

References


[1] Garg HP, Datta G. Global Status on Renewable Energy. Solar Energy Heating and Cooling Methods in Buildings, International Workshop, Iran University of Science and Technology 1998; 19-20.
[2] Demirba A, Arin G. An Overview of Biomass Pyrolysis. Energ Source 2002; 24: 471-82. http://dx.doi.org/10.1080/00908310252889979
[3] Hall DO, Hemstock SL, House J. Rosillo-CaUe F. Biomass energy and the global carbon balance. In Renewable Energy and the Environment (edited by A. A. M. Sayigh). New York: Pergamon Press 1992.
[4] Demirba A. Biorefinery Technologies for Biomass Upgrading, Energ Source Part A 2010; 32: 1547-58. http://dx.doi.org/10.1080/15567030902780394
[5] Demirba A. Products from Lignocellulosic Materials via Degradation Processes. Energ Source Part A 2008; 30(1): 27-37. http://dx.doi.org/10.1080/00908310600626705
[6] Özçimen D. Ersoy-Meriçboyu A. A study on the carbonization of grapeseed and chestnut shell. Fuel Process Technol 2008; 89: 1041-46. http://dx.doi.org/10.1016/j.fuproc.2008.04.006
[7] Mckendry P. Energy production from biomass (part 1): Overview of biomass. Bioresource Technol 2002; 83: 37-46. http://dx.doi.org/10.1016/S0960-8524(01)00118-3
[8] Nisar J, Ali M, Awan IA. Catalytic Thermal Decomposition of Polyethylene by Pyrolysis Gas Chromatography. Chil Chem Soc 2011; 56(2): 653-55. http://dx.doi.org/10.4067/S0717-97072011000200006
[9] Williams PT, Nugranad N. Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks. Energy 2000; 25: 493-13. http://dx.doi.org/10.1016/S0360-5442(00)00009-8
[10] French R, Czernik S. Catalytic pyrolysis of biomass for biofuels production. Fuel Process Technol 2010; 91: 25-32. http://dx.doi.org/10.1016/j.fuproc.2009.08.011
[11] Carlson TR, Tompsett GA, Conner WC, Huber GW. Aromatic production from catalytic fast pyrolysis of biomass-derived feedstocks. Top Catal 2009; 52: 241-52. http://dx.doi.org/10.1007/s11244-008-9160-6
[12] Thangalazhy-Gopakumar S, Adhikari S, Chattanathan SA. Gupta RB. Catalytic pyrolysis of green algae for hydrocarbon production using H+ZSM-5 catalyst. Bioresource Technol 2012; 118: 150-57. http://dx.doi.org/10.1016/j.biortech.2012.05.080
[13] Aysu T, Turhan M, Küçük MM. Liquefaction of Typha latifolia by supercritical fluid extraction. Bioresource Technol 2012; 107: 464-70. http://dx.doi.org/10.1016/j.biortech.2011.12.069
[14] Aysu T, Küçük MM. Liquefaction of Giant Reed (Arundo donax L.) by Supercritical Fluid Extraction. Fuel 2013; 103: 758-63. http://dx.doi.org/10.1016/j.fuel.2012.07.001
[15] Aysu T. Supercritical fluid extraction of reed canary grass (Phalaris arundinacea). Biomass Bioenerg 2012; 41: 139-44. http://dx.doi.org/10.1016/j.biombioe.2012.02.024
[16] Pimenov MG, Leonov MV. The Asian Umbelliferae biodiversity database (ASIUM) with particular reference to South-West Asian Taxa. Turk J Bot 2004: 28: 139-45.
[17] Rechinger KH. Apiaceae. In Flora Iranica. Graz: Akademische Druck-u.Verlagsanstalt 1982.
[18] Amin G. Popular medicinal plants of Iran. Tehran: Tehran University of Medical Sciences Press 2008.
[19] Naraghi M. Medicinal flowers and plants. Tehran: Amir Kabir Publications 1972.
[20] Zargari A. Medicinal plants (Vol. 2). Tehran: Tehran University Publications 1988.
[21] Firuzi O, Asadollahi M, Gholami M, Javidnia K. Composition and biological activities of essential oils from four Heracleum species. Food Chem 2010; 122: 117-22. http://dx.doi.org/10.1016/j.foodchem.2010.02.026
[22] Tappi Test Methods. Tappi Press, Atlanta, Georgia 1998.
[23] Luo Z, Wang S, Liao Y, Zhou J, Gu Y, Cen K. Research on biomass fast pyrolysis for liquid fuel. Biomass Bioenerg 2004; 26: 455-62. http://dx.doi.org/10.1016/j.biombioe.2003.04.001
[24] Erta M, Alma MH. Pyrolysis of laurel (Laurus nobilis L.) extraction residues in a fixed-bed reactor: Characterization of bio-oil and bio-char. J Anal Appl Pyrol 2010; 88: 22-29. http://dx.doi.org/10.1016/j.jaap.2010.02.006
[25] Onay Ö. Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor. Fuel Process Technol 2007; 88: 523-31. http://dx.doi.org/10.1016/j.fuproc.2007.01.001
[26] Demiral , ensöz S. Fixed-Bed Pyrolysis of Hazelnut (Corylus Avellana L.) Bagasse: Influence of Pyrolysis Parameters on Product Yields. Energ Source Part A 2006; 28(12): 1149-58. http://dx.doi.org/10.1080/009083190966126
[27] Kele S, Kaygusuz K, Akgün M. Pyrolysis of Woody Biomass for Sustainable Bio-oil. Energ Source Part A 2011; 33(9): 879-89. http://dx.doi.org/10.1080/15567030903330652
[28] Nishimura M, Iwasaki S, Horio M. The role of potassium carbonate on cellulose pyrolysis. J Taiwan Inst Chem E 2009; 40 (6): 630-37. http://dx.doi.org/10.1016/j.jtice.2009.05.005
[29] Adams RP. Identification of Essential Oil Components by Gas Chromatograph/ Quadrupole Mass Spectroscopy. 4th ed. Carol Stream IL: Allured Publishing Corporation 2007.

Downloads

Published

2013-11-25

How to Cite

Aysu, T. (2013). Production and Characterization of Bio-Chars and Bio-Oils Formed by Pyrolysis of Persian Hogweed (Heracleum persicum Desf.) in A Fixed-Bed Reactor. Journal of Applied Solution Chemistry and Modeling, 2(4), 205–215. https://doi.org/10.6000/1929-5030.2013.02.04.1

Issue

Section

General Articles