Mechanical and Morphological Analysis of 3D-Printed Polylactic Acid-Polybutylene Adipate Terephthalate Composite
DOI:
https://doi.org/10.6000/1929-5995.2026.15.03Keywords:
Polylactic Acid, Polybutylene Adipate Terephthalate, Polymer blends, Fused Deposition Modeling, Infill density, Mechanical properties, Dynamic Mechanical Analysis, Scanning Electron Microscopy, Biodegradable polymers, Additive ManufacturingAbstract
In this research paper, a detailed examination of the mechanical properties and morphologies of PLA and PBAT polymer blend materials which were produced through 3D printing techniques was conducted. The examination was completed using a PLA/PBAT/Joncryl blended material with a composition ratio of 77/20/3 wt% and manufactured through FDM techniques and an experimental design technique known as the Taguchi method to evaluate the effects of various manufacturing parameters on the mechanical characteristics of the material. This study investigates the mechanical and morphological performance of FDM-printed PLA/PBAT/Joncryl blend specimens using a Taguchi L9 design. A PLA/PBAT/Joncryl blend (77/20/3 wt%) was fabricated and printed by varying layer height (0.16–0.24 mm), printing temperature (190–210 °C), and infill density (50–100%). The optimal condition (0.16 mm, 210 °C, 100% infill) produced a maximum tensile strength of 41.20 N/mm² and elongation of 12.42%. ANOVA results confirmed infill density as the most significant parameter contributing 81.35% of the variance (P = 0.009). SEM revealed reduced voids and improved interlayer fusion at higher infill levels, while DMA showed higher storage modulus (~2200 MPa) for 100% infill specimens. The findings provide a process–structure–property relationship for optimizing biodegradable PLA/PBAT components for high-strength applications. This study illustrates that the infill % is the primary parameter that should be adjusted, while the layer height and printing temperature contribute but to a lesser extent to the improved performance of biodegradable PLA/PBAT/Joncryl blends.
References
Mobarak MH, Abid AS, Munna MS, Dutta M, Rimon MIH. Additive manufacturing in biomedical: Applications, challenges, and prospects. Hybrid Advances 2025; 10: 100467. DOI: https://doi.org/10.1016/j.hybadv.2025.100467
Gao W, Zhang Y, Ramanujan D, Ramani K, Chen Y, Williams CB, Wang CC, Shin YC, Zhang S, Zavattieri PD. The status, challenges, and future of additive manufacturing in engineering. Computer-Aided Design 2015; 69: 65-89. DOI: https://doi.org/10.1016/j.cad.2015.04.001
Kristiawan RB, Imaduddin F, Ariawan D, Ubaidillah, Arifin Z. A review on the fused deposition modeling (FDM) 3D printing: Filament processing, materials, and printing parameters. Open Engineering 2021; 11(1): 639-649. DOI: https://doi.org/10.1515/eng-2021-0063
Turner BN, Gold SA. A review of melt extrusion additive manufacturing processes: II. Materials, dimensional accuracy, and surface roughness. Rapid Prototyping Journal 2015; 21(3): 250-261. DOI: https://doi.org/10.1108/RPJ-02-2013-0017
Samir A, Ashour FH, Hakim AA, Bassyouni M. Recent advances in biodegradable polymers for sustainable applications. Npj Materials Degradation 2022; 6(1): 68. DOI: https://doi.org/10.1038/s41529-022-00277-7
Auras RA, Lim LT, Selke SE, Tsuji H, Eds. Poly (lactic acid): synthesis, structures, properties, processing, applications, and end of life. John Wiley & Sons 2022. DOI: https://doi.org/10.1002/9781119767480
Farah S, Anderson DG, Langer R. Physical and mechanical properties of PLA, and their functions in widespread applications—A comprehensive review. Advanced Drug Delivery Reviews 2016; 107: 367-392. DOI: https://doi.org/10.1016/j.addr.2016.06.012
Taubner M, Shishoo R. Influence of processing parameters on the degradation of PLA during extrusion. Polymer Degradation and Stability 1998; 59(1-3): 213-220.
Taghinezhad SF, Mansourieh M, Abbasi A, Major I, Pezzoli R. Improved compatibilized TPS/PLA blends: effects of singular and binary compatibilization systems. Carbohydrate Polymer Technologies and Applications 2025; p. 100819. DOI: https://doi.org/10.1016/j.carpta.2025.100819
Taleb K, Saidi-Besbes S, Pillin I, Grohens Y. Biodegradable poly (butylene succinate) nanocomposites based on dimeric surfactant organomodified clays with enhanced water vapor barrier and mechanical properties. ACS Omega 2022; 7(47): 43254-43264. DOI: https://doi.org/10.1021/acsomega.2c05964
Shen Y, Jin B, Ren L, Gan H, Li J, Zhao D, Shen H, Zhang M. Fully Biodegradable Poly (lactic acid)/Poly (butylene adipate-co-terephthalate) Blends with highly toughness Based on in situ Interfacial Compatibilization by functional epoxy compound 2025. DOI: https://doi.org/10.21203/rs.3.rs-6564026/v1
Wang D, Li Y, Xie XM, Guo BH. Compatibilization and morphology development of immiscible ternary polymer blends. Polymer 2011; 52(1): 191-200. DOI: https://doi.org/10.1016/j.polymer.2010.11.019
He H, Wang G, Chen M, Xiong C, Li Y, Tong Y. Effect of different compatibilizers on the properties of poly (lactic acid)/ poly (butylene adipate-co-terephthalate) blends prepared under intense shear flow field. Materials 2020; 13(9): 2094. DOI: https://doi.org/10.3390/ma13092094
Lendvai L, Brenn D. Mechanical, morphological and thermal characterization of compatibilized poly (lactic acid)/thermoplastic starch blends. Acta Technica Jaurinensis 2020; 13(1): 1-13. DOI: https://doi.org/10.14513/actatechjaur.v13.n1.532
Oguz H, Dogan C, Kara D, Ozen ZT, Ovali D, Nofar M. Development of PLA-PBAT and PLA-PBSA bio-blends: Effects of processing type and PLA crystallinity on morphology and mechanical properties. In AIP Conference Proceedings. AIP Publishing LLC 2019; 2055(1): 030003. DOI: https://doi.org/10.1063/1.5084813
Ning F, Cong W, Qiu J, Wei J, Wang S. Additive manufacturing of carbon fiber reinforced thermoplastic composites using fused deposition modeling. Composites Part B: Engineering 2015; 80: 369-378. DOI: https://doi.org/10.1016/j.compositesb.2015.06.013
Gonzalez YE, Mendoza JM, Durán JR, Vertel LCT, Rhenals-Julio JD. Effect of printing parameters on mechanical properties and processing time of additively manufactured parts. Matéria (Rio de Janeiro) 2023; 28: e20230111. DOI: https://doi.org/10.1590/1517-7076-rmat-2023-0111
Popescu D, Zapciu A, Amza C, Baciu F, Marinescu R. FDM process parameters influence over the mechanical properties of polymer specimens: A review. Polymer Testing 2018; 69: 157-166. DOI: https://doi.org/10.1016/j.polymertesting.2018.05.020
Zolfagharian A, Khosravani MR, Kaynak A. Fracture resistance analysis of 3D-printed polymers. Polymers 2020; 12(2): 302. DOI: https://doi.org/10.3390/polym12020302
Bhiogade A, Kannan M. Studies on thermal and degradation kinetics of cellulose micro/nanoparticle filled polylactic acid (PLA) based nanocomposites. Polymers and Polymer Composites 2021; 29(9_suppl): S85-S98. DOI: https://doi.org/10.1177/0967391120987170
Gonabadi H, Yadav A, Bull SJ. The effect of processing parameters on the mechanical characteristics of PLA produced by a 3D FFF printer. The International Journal of Advanced Manufacturing Technology 2020; 111: 695-709. DOI: https://doi.org/10.1007/s00170-020-06138-4
Müller M, Valášek J, Šleger M. Effect of infill density in FDM 3D printing on low-cycle fatigue behavior of PLA materials. Polymers 2022; 14(22): 4930. DOI: https://doi.org/10.3390/polym14224930
Turaka S, Prasad ASG, Reddy AK, Naidu MT. Impact of infill density on morphology and mechanical performance of MEX/FFF manufactured polymer composite components Heliyon 2024; 10. DOI: https://doi.org/10.1016/j.heliyon.2024.e29920
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